By the time they arrived at the station, the train         .

A．will leaveB．would leave
C．has leftD．had left

D

解析試題分析：句意：到他們到達(dá)火車站是，火車已經(jīng)離開了。根據(jù)By the time they arrived at the station,可知到達(dá)這個(gè)動(dòng)作發(fā)生在過(guò)去，火車離開是在他們到達(dá)之前，故用過(guò)去完成時(shí)。故選D。
考點(diǎn)：考查時(shí)態(tài)的用法。

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